IAAC Apps

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁴⁺

MeCN

-

0.838

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁴⁺

MeCN

Pt

[N₂₂₂₂][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
48	WE	-	0.722	-	-	± 0.003	25.0	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁴⁺	MeCN	[N₂₂₂₂][PF₆]	Pt	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	SCE	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	6
50	WE	-	0.322	-	-	± 0.003	25.0	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁴⁺	MeCN	[N₂₂₂₂][PF₆]	Pt	Fc⁺ / Fc	MeCN	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	-	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	4

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁶⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺

MeCN

-

1.126

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁶⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺

MeCN

Pt

[N₂₂₂₂][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
49	WE	-	1.005	-	-	± 0.003	25.0	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁶⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺	MeCN	[N₂₂₂₂][PF₆]	Pt	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	SCE	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	6
51	WE	-	0.610	-	-	± 0.003	25.0	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁶⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺	MeCN	[N₂₂₂₂][PF₆]	Pt	Fc⁺ / Fc	MeCN	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	-	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	4

Ideal Half Cells

▶	Select	Redoxsystem	Solvent	E^°_abs / V	E_{1/2, abs} / V	E_{pa, abs} / V	E_{pc, abs} / V	Uncertainty / V	Quality

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

Ag⁺ / Ag

1FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

1FB

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
10	RE	-	-0.740	-	-	-	25.0	Ag⁺ / Ag	1FB	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	1FB	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

2FB

-

1.647

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

2FB

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
11	RE	-	-0.990	-	-	-	25.0	Ag⁺ / Ag	2FB	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	2FB	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

3FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

3FB

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
12	RE	-	-1.260	-	-	-	25.0	Ag⁺ / Ag	3FB	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	3FB	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

4FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

4FB

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
13	RE	-	-1.470	-	-	-	25.0	Ag⁺ / Ag	4FB	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	4FB	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

5FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

5FB

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
14	RE	-	-1.500	-	-	-	25.0	Ag⁺ / Ag	5FB	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	5FB	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

DCE

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

DCE

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
16	RE	-	-0.660	-	-	-	25.0	Ag⁺ / Ag	DCE	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	DCE	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

DCM

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

DCM

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
15	RE	-	-0.880	-	-	-	25.0	Ag⁺ / Ag	DCM	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	DCM	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

DMF

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

DMF

Ag

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
82	WE	-0.221	-	-	-	± 0.006	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	H₂O	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
84	WE	0.039	-	-	-	± 0.006	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	MeCN	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
86	WE	-0.385	-	-	-	± 0.006	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	PC	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
89	RE	0.215	-	-	-	± 0.005	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	H₂O	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
93	RE	-0.041	-	-	-	± 0.005	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	MeCN	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
96	RE	0.380	-	-	-	± 0.005	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	PC	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
99	WE	-0.235	-	-	-	± 0.005	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	EtOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
100	WE	-0.257	-	-	-	± 0.005	25.0	Ag⁺ / Ag	DMF	-	Ag	Ag⁺ / Ag	MeOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2

Ag⁺ / Ag

DMF

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
17	RE	-	-0.110	-	-	-	25.0	Ag⁺ / Ag	DMF	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	DMF	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Ag⁺ / Ag

EMC , EC (0.7:0.3)

1.223

-

± 0.101

2

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

EMC , EC (0.7:0.3)

Ag

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
63	RE	-0.254	-	-	-	± 0.100	25.0	Ag⁺ / Ag	EMC , EC (0.7:0.3)	-	Ag	Ag⁺ / Ag	H₂O	Ag	AgNTf₂	AgNTf₂	OCV; ILSB	Carina MA	2

Ag⁺ / Ag

EMC , EC (0.7:0.3)

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
54	RE	-0.491	-	-	-	-	25.0	Ag⁺ / Ag	EMC , EC (0.7:0.3)	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	EMC , EC (0.7:0.3)	Pt	Fc	Agpf	CV	gemessen Timo	4

🔗

Ag⁺ / Ag

H₂O

0.799

-

1

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

H₂O

Ag

-

1

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
24	WE	0.799	-	-	-	-	25.0	Ag⁺ / Ag	H₂O	-	Ag	H⁺ / H₂	H₂O	Pt	-	-	OCV	CRC	1

Ag⁺ / Ag

H₂O

Ag

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
61	RE	-0.433	-	-	-	± 0.010	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	OCV; ILSB	Denis	2
63	WE	-0.254	-	-	-	± 0.100	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	EMC , EC (0.7:0.3)	Ag	AgNTf₂	AgNTf₂	OCV; ILSB	Carina MA	2
81	RE	-0.260	-	-	-	± 0.006	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	MeCN	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
82	RE	-0.221	-	-	-	± 0.006	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	DMF	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
83	RE	0.164	-	-	-	± 0.006	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	PC	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
87	WE	0.256	-	-	-	± 0.005	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	MeCN	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
88	WE	-0.165	-	-	-	± 0.005	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	PC	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
89	WE	0.215	-	-	-	± 0.005	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	DMF	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
90	WE	-0.020	-	-	-	± 0.005	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	EtOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
91	WE	-0.042	-	-	-	± 0.005	25.0	Ag⁺ / Ag	H₂O	-	Ag	Ag⁺ / Ag	MeOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2

🔗

Ag⁺ / Ag

MeCN

0.536

-

± 0.014

2

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

MeCN

Ag

-

[C₈MIm][FAP]

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
60	WE	-0.443	-	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	OCV; ILSB	Timo FP	3

Ag⁺ / Ag

MeCN

Ag

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
57	RE	-0.031	-	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	-	Ag	H⁺ / H₂	MeCN	Pt	H₂ , HNTf₂	Agpf	OCV; ILSB	Razan	2
59	WE	-0.433	-	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	OCV; ILSB	Denis	2
61	WE	-0.433	-	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	H₂O	Ag	Agpf	Agpf	OCV; ILSB	Denis	2
73	WE	1.000	-	-	-	-	-	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	ILSB	test	2
74	WE	1.000	-	-	-	-	-	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	ILSB	test	2
75	WE	1.000	-	-	-	± 1.000	34.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC (1.0)	Ag	Agpf , Silver bromide	Agpf , Silver bromide	ILSB	test	2
76	WE	1.000	-	-	-	-	34.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	ILSB	test	2
77	WE	1.000	-	-	-	-	-	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	ILSB	test	2
78	WE	2.000	-	-	-	-	-	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	ILSB	edit test	2
81	WE	-0.260	-	-	-	± 0.006	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	H₂O	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
84	RE	0.039	-	-	-	± 0.006	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	DMF	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
85	RE	0.424	-	-	-	± 0.006	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
87	RE	0.256	-	-	-	± 0.005	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	H₂O	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
92	WE	-0.422	-	-	-	± 0.005	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
93	WE	-0.041	-	-	-	± 0.005	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	DMF	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
94	WE	-0.276	-	-	-	± 0.005	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	EtOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
95	WE	-0.298	-	-	-	± 0.005	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	MeOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
127	WE	0.034	-	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	-	Ag	H⁺ / H₂	MeCN	Pt	Agpf	HNTf₂ , H₂	OCV	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2

Ag⁺ / Ag

MeCN

Ag

-

[N₁₈₈₈][pf]

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
58	RE	0.455	-	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC	Ag	Agpf	Agpf	OCV; ILSB	Timo MA	3

Ag⁺ / Ag

MeCN

Ag

-

1-Butyl-3-methylimidazolium chloride

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
71	WE	1.000	-	-	-	-	-	Ag⁺ / Ag	MeCN	-	Ag	Ag⁺ / Ag	PC (1.0)	Ag	Silver fluoride , Silver bromide	Silver fluoride , Silver bromide	ILSB	test	3

Ag⁺ / Ag

MeCN

Ag

[N₂₂₂₂][ClO₄]

0.200

1.000

-

5

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
34	RE	-	-1.367	-	-	-	25.0	Ag⁺ / Ag	MeCN	[N₂₂₂₂][ClO₄]	Ag	Cc⁺ / Cc	MeCN	Hg oder Pt	CcPF₆	AgClO₄ , AgNO₃	CV	T. Kakutani, Y. Morihiro, M. Senda, R. Takahashi, K. Matsumoto, Bull. Chem. Soc. Jpn. 1978, 51, 2847-2854. DOI: 10.1246/bcsj.51.2847	5
35	RE	-	-2.297	-	-	-	25.0	Ag⁺ / Ag	MeCN	[N₂₂₂₂][ClO₄]	Ag	Cc / Cc^-	MeCN	Hg oder Pt	CcPF₆	AgClO₄ , AgNO₃	CV	T. Kakutani, Y. Morihiro, M. Senda, R. Takahashi, K. Matsumoto, Bull. Chem. Soc. Jpn. 1978, 51, 2847-2854. DOI: 10.1246/bcsj.51.2847	5

Ag⁺ / Ag

MeCN

Ag

[N₄₄₄₄][pf]

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
79	WE	-	1.500	-	-	± 0.010	25.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][pf]	Ag	Cl₂ / Cl^-	MeCN (1.0)	Pt	Agpf	Cl₂	CV	R.A. Musgrave, A.D. Russell, P.R. Gamm, R.L.N. Hailes, K. Lam, H.A. Sparkes, J.C. Green, W.E. Geiger, I. Manners, Organometallics 2021, 40, 1945-1955. DOI: 10.1021/acs.organomet.1c00247	4

Ag⁺ / Ag

MeCN

Ag

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
67	WE	-	-	1.000	-	± 0.100	300.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	MeCN	Pt	Agpf	Fcpf , Fc	trst	test	4

Ag⁺ / Ag

MeCN

Ag

[N₄₄₄₄][pf]

0.100

0.001

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality

Ag⁺ / Ag

MeCN

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
18	RE	-	-0.020	-	-	-	25.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	MeCN	Pt	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

Ag⁺ / Ag

MeCN

Ag

[N₄₄₄₄][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
30	WE	0.128	-	-	-	± 0.002	25.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][PF₆]	Ag	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	AgClO₄	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
31	WE	0.237	-	-	-	± 0.002	25.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][PF₆]	Ag	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	AgNO₃	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
32	WE	0.225	-	-	-	± 0.002	25.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][PF₆]	Ag	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	AgNO₃	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
33	WE	0.121	-	-	-	± 0.002	25.0	Ag⁺ / Ag	MeCN	[N₄₄₄₄][PF₆]	Ag	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	AgNO₃	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6

Ag⁺ / Ag

MeCN

Ag

1-Ethyl-3-methylimidazolium chloride

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
72	WE	-	1.000	-	-	-	-	Ag⁺ / Ag	MeCN	1-Ethyl-3-methylimidazolium chloride	Ag	Fc⁺ / Fc	MeCN (1.0)	Pt	Agpf	Fcpf , Fc	CV	test	4

🔗

Ag⁺ / Ag

PC

0.969

-

± 0.017

2

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Ag⁺ / Ag

PC

Ag

-

[C₈MIm][FAP]

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
60	RE	-0.443	-	-	-	± 0.010	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	OCV; ILSB	Timo FP	3

Ag⁺ / Ag

PC

Ag

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
59	RE	-0.433	-	-	-	± 0.010	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	OCV; ILSB	Denis	2
73	RE	1.000	-	-	-	-	-	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	ILSB	test	2
76	RE	1.000	-	-	-	-	34.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	ILSB	test	2
77	RE	1.000	-	-	-	-	-	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	ILSB	test	2
78	RE	2.000	-	-	-	-	-	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	ILSB	edit test	2
83	WE	0.164	-	-	-	± 0.006	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	H₂O	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
85	WE	0.424	-	-	-	± 0.006	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
86	RE	-0.385	-	-	-	± 0.006	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	DMF	Ag	-	-	OCV; ILSB	V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2022, 28. DOI: 10.1002/chem.202200509	2
88	RE	-0.165	-	-	-	± 0.005	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	H₂O	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
92	RE	-0.422	-	-	-	± 0.005	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
96	WE	0.380	-	-	-	± 0.005	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	DMF	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
97	WE	0.145	-	-	-	± 0.005	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	EtOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2
98	WE	0.124	-	-	-	± 0.005	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeOH	Ag	-	-	OCV; ILSB	V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chemistry A European J 2023, 29. DOI: 10.1002/chem.202300609	2

Ag⁺ / Ag

PC

Ag

-

1.000

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
75	RE	1.000	-	-	-	± 1.000	34.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf , Silver bromide	Agpf , Silver bromide	ILSB	test	2

Ag⁺ / Ag

PC

Ag

-

[N₁₈₈₈][pf]

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
58	WE	0.455	-	-	-	± 0.010	25.0	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN	Ag	Agpf	Agpf	OCV; ILSB	Timo MA	3

Ag⁺ / Ag

PC

Ag

-

1-Butyl-3-methylimidazolium chloride

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
71	RE	1.000	-	-	-	-	-	Ag⁺ / Ag	PC	-	Ag	Ag⁺ / Ag	MeCN (1.0)	Ag	Silver fluoride , Silver bromide	Silver fluoride , Silver bromide	ILSB	test	3

Ag⁺ / Ag

PC

Ag

[N₂₂₂₂][ClO₄]

0.200

1.000

-

5

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
53	RE	-	-1.807	-	-	-	25.0	Ag⁺ / Ag	PC	[N₂₂₂₂][ClO₄]	Ag	Cc⁺ / Cc	PC	Hg oder Pt	CcPF₆	AgClO₄ , AgNO₃	CV	T. Kakutani, Y. Morihiro, M. Senda, R. Takahashi, K. Matsumoto, Bull. Chem. Soc. Jpn. 1978, 51, 2847-2854. DOI: 10.1246/bcsj.51.2847	5

Ag⁺ / Ag

PC

Ag

[N₄₄₄₄][pf]

0.100

1.000

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
25	RE	-	-0.491	-	-	-	25.0	Ag⁺ / Ag	PC	[N₄₄₄₄][pf]	Ag	Fc⁺ / Fc	PC	Pt	Fcpf	Agpf	CV	gemessen Timo	4

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

AgCl / Cl^- , Ag

H₂O | MeCN

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

AgCl / Cl^- , Ag

H₂O | MeCN

Ag

[N₄₄₄₄][BF₄]

0.100

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
55	RE	-	1.290	-	-	-	25.0	AgCl / Cl^- , Ag	H₂O \| MeCN	[N₄₄₄₄][BF₄]	Ag	[Ru(bpy)₃]³⁺ / [Ru(bpy)₃]²⁺	MeCN	Pt	-	SSCE	CV	J. G. Gaudiello, P. R. Sharp, A. J. Bard, J. Am. Chem. Soc. 1982, 104, 6373.	6

Ideal Half Cells

▶	Select	Redoxsystem	Solvent	E^°_abs / V	E_{1/2, abs} / V	E_{pa, abs} / V	E_{pc, abs} / V	Uncertainty / V	Quality

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

Cc / Cc^-

MeCN

-

-1.782

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Cc / Cc^-

MeCN

Au

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
41	WE	-	-2.300	-	-	-	25.0	Cc / Cc^-	MeCN	[N₄₄₄₄][BF₄]	Au	Fc⁺ / Fc	MeCN	Au	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Cc / Cc^-

MeCN

DME

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
46	WE	-	-1.920	-	-	± 0.001	25.0	Cc / Cc^-	MeCN	[N₄₄₄₄][BF₄]	DME	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	CcBr₃	SCE	CV	S. Gubin, S. Smirnova, L. Denisovich, Journal of Organometallic Chemistry 1971, 30, 257-265. DOI: 10.1016/S0022-328X(00)90205-5	6

Cc / Cc^-

MeCN

HMDE

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
37	WE	-	-2.298	-	-	-	25.0	Cc / Cc^-	MeCN	[N₄₄₄₄][BF₄]	HMDE	Fc⁺ / Fc	MeCN	HMDE	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Cc / Cc^-

MeCN

Hg oder Pt

[N₂₂₂₂][ClO₄]

0.200

-

5

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
35	WE	-	-2.297	-	-	-	25.0	Cc / Cc^-	MeCN	[N₂₂₂₂][ClO₄]	Hg oder Pt	Ag⁺ / Ag	MeCN	Ag	CcPF₆	AgClO₄ , AgNO₃	CV	T. Kakutani, Y. Morihiro, M. Senda, R. Takahashi, K. Matsumoto, Bull. Chem. Soc. Jpn. 1978, 51, 2847-2854. DOI: 10.1246/bcsj.51.2847	5

Cc / Cc^-

MeCN

Pt

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
43	WE	-	-2.297	-	-	-	25.0	Cc / Cc^-	MeCN	[N₄₄₄₄][BF₄]	Pt	Fc⁺ / Fc	MeCN	Pt	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Cc / Cc^-

MeCN

glassy carbon

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
39	WE	-	-2.297	-	-	-	25.0	Cc / Cc^-	MeCN	[N₄₄₄₄][BF₄]	glassy carbon	Fc⁺ / Fc	MeCN	glassy carbon	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

Cc⁺ / Cc

MeCN

-

-0.831

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Cc⁺ / Cc

MeCN

Au

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
40	WE	-	-1.345	-	-	-	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][BF₄]	Au	Fc⁺ / Fc	MeCN	Au	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Cc⁺ / Cc

MeCN

DME

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
45	WE	-	-0.980	-	-	± 0.001	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][BF₄]	DME	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	CcBr₃	SCE	CV	S. Gubin, S. Smirnova, L. Denisovich, Journal of Organometallic Chemistry 1971, 30, 257-265. DOI: 10.1016/S0022-328X(00)90205-5	6

Cc⁺ / Cc

MeCN

HMDE

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
36	WE	-	-1.347	-	-	-	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][BF₄]	HMDE	Fc⁺ / Fc	MeCN	HMDE	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Cc⁺ / Cc

MeCN

Hg oder Pt

[N₂₂₂₂][ClO₄]

0.200

-

5

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
34	WE	-	-1.367	-	-	-	25.0	Cc⁺ / Cc	MeCN	[N₂₂₂₂][ClO₄]	Hg oder Pt	Ag⁺ / Ag	MeCN	Ag	CcPF₆	AgClO₄ , AgNO₃	CV	T. Kakutani, Y. Morihiro, M. Senda, R. Takahashi, K. Matsumoto, Bull. Chem. Soc. Jpn. 1978, 51, 2847-2854. DOI: 10.1246/bcsj.51.2847	5

Cc⁺ / Cc

MeCN

Pt

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
42	WE	-	-1.352	-	-	-	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][BF₄]	Pt	Fc⁺ / Fc	MeCN	Pt	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Cc⁺ / Cc

MeCN

Pt

[N₄₄₄₄][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
47	WE	-	-0.945	-	-	± 0.001	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][PF₆]	Pt	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	-	SCE	CV	U. Koelle, Journal of Organometallic Chemistry 1978, 152, 225-228. DOI: 10.1016/S0022-328X(00)91926-0	6

Cc⁺ / Cc

MeCN

dme?

[N₄₄₄₄][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
44	WE	-	-0.905	-	-	-	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][PF₆]	dme?	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	CcPF₆	SCE	CV	T. Gennett, D.F. Milner, M.J. Weaver, J. Phys. Chem. 1985, 89, 2787-2794. DOI: 10.1021/j100259a018	6

Cc⁺ / Cc

MeCN

glassy carbon

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
38	WE	-	-1.348	-	-	-	25.0	Cc⁺ / Cc	MeCN	[N₄₄₄₄][BF₄]	glassy carbon	Fc⁺ / Fc	MeCN	glassy carbon	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

🔗

Cc⁺ / Cc

PC

-

-0.838

-

5

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Cc⁺ / Cc

PC

Hg oder Pt

[N₂₂₂₂][ClO₄]

0.200

-

5

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
53	WE	-	-1.807	-	-	-	25.0	Cc⁺ / Cc	PC	[N₂₂₂₂][ClO₄]	Hg oder Pt	Ag⁺ / Ag	PC	Ag	CcPF₆	AgClO₄ , AgNO₃	CV	T. Kakutani, Y. Morihiro, M. Senda, R. Takahashi, K. Matsumoto, Bull. Chem. Soc. Jpn. 1978, 51, 2847-2854. DOI: 10.1246/bcsj.51.2847	5

Ideal Half Cells

▶	Select	Redoxsystem	Solvent	E^°_abs / V	E_{1/2, abs} / V	E_{pa, abs} / V	E_{pc, abs} / V	Uncertainty / V	Quality

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

Cr(C₆H₆)⁺ / Cr(C₆H₆)

MeCN

-

-0.471

-

6

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Cr(C₆H₆)⁺ / Cr(C₆H₆)

MeCN

dme?

[N₄₄₄₄][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
52	WE	-	-0.770	-	-	-	25.0	Cr(C₆H₆)⁺ / Cr(C₆H₆)	MeCN	[N₄₄₄₄][PF₆]	dme?	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	Cr(C₆H₆)	SCE	CV	T. Gennett, D.F. Milner, M.J. Weaver, J. Phys. Chem. 1985, 89, 2787-2794. DOI: 10.1021/j100259a018	6

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

Fc⁺ / Fc

1FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

1FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
1	RE	-	1.110	-	-	-	25.0	Fc⁺ / Fc	1FB	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	1FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
10	WE	-	-0.740	-	-	-	25.0	Fc⁺ / Fc	1FB	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	1FB	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
19	RE	-	0.690	-	-	-	25.0	Fc⁺ / Fc	1FB	[N₄₄₄₄][pf]	Pt	MB⋅⁺ / MB	1FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

2FB

0.657

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

2FB

Pt

-

[N₁₈₈₈][pf]

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
62	WE	0.142	-	-	-	± 0.020	25.0	Fc⁺ / Fc	2FB	-	Pt	Fc⁺ / Fc	MeCN	Pt	Fcpf , Fc	Fcpf , Fc	OCV; ILSB	Tanja MA	3

Fc⁺ / Fc

2FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
2	RE	-	1.230	-	-	-	25.0	Fc⁺ / Fc	2FB	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	2FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
11	WE	-	-0.990	-	-	-	25.0	Fc⁺ / Fc	2FB	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	2FB	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
20	RE	-	0.690	-	-	-	25.0	Fc⁺ / Fc	2FB	[N₄₄₄₄][pf]	Pt	MB⋅⁺ / MB	2FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

3FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

3FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
3	RE	-	1.420	-	-	-	25.0	Fc⁺ / Fc	3FB	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	3FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
12	WE	-	-1.260	-	-	-	25.0	Fc⁺ / Fc	3FB	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	3FB	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
21	RE	-	0.690	-	-	-	25.0	Fc⁺ / Fc	3FB	[N₄₄₄₄][pf]	Pt	MB⋅⁺ / MB	3FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

4FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

4FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
4	RE	-	1.520	-	-	-	25.0	Fc⁺ / Fc	4FB	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	4FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
13	WE	-	-1.470	-	-	-	25.0	Fc⁺ / Fc	4FB	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	4FB	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
22	RE	-	0.690	-	-	-	25.0	Fc⁺ / Fc	4FB	[N₄₄₄₄][pf]	Pt	MB⋅⁺ / MB	4FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

5FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

5FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
5	RE	-	1.470	-	-	-	25.0	Fc⁺ / Fc	5FB	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	5FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
14	WE	-	-1.500	-	-	-	25.0	Fc⁺ / Fc	5FB	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	5FB	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
23	RE	-	0.690	-	-	-	25.0	Fc⁺ / Fc	5FB	[N₄₄₄₄][pf]	Pt	MB⋅⁺ / MB	5FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

DCE

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

DCE

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
7	RE	-	1.230	-	-	-	25.0	Fc⁺ / Fc	DCE	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	DCE	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
16	WE	-	-0.660	-	-	-	25.0	Fc⁺ / Fc	DCE	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	DCE	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

DCM

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

DCM

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
6	RE	-	1.400	-	-	-	25.0	Fc⁺ / Fc	DCM	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	DCM	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
15	WE	-	-0.880	-	-	-	25.0	Fc⁺ / Fc	DCM	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	DCM	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

DMF

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

DMF

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
8	RE	-	0.540	-	-	-	25.0	Fc⁺ / Fc	DMF	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	DMF	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
17	WE	-	-0.110	-	-	-	25.0	Fc⁺ / Fc	DMF	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	DMF	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

Fc⁺ / Fc

EMC , EC (0.7:0.3)

0.732

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

EMC , EC (0.7:0.3)

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
54	WE	-0.491	-	-	-	-	25.0	Fc⁺ / Fc	EMC , EC (0.7:0.3)	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	EMC , EC (0.7:0.3)	Ag	Fc	Agpf	CV	gemessen Timo	4

🔗

Fc⁺ / Fc

MeCN

-

0.516

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

MeCN

Au

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
40	RE	-	-1.345	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	Au	Cc⁺ / Cc	MeCN	Au	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4
41	RE	-	-2.300	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	Au	Cc / Cc^-	MeCN	Au	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Fc⁺ / Fc

MeCN

HMDE

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
36	RE	-	-1.347	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	HMDE	Cc⁺ / Cc	MeCN	HMDE	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4
37	RE	-	-2.298	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	HMDE	Cc / Cc^-	MeCN	HMDE	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Fc⁺ / Fc

MeCN

Pt

-

[N₁₈₈₈][pf]

3

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
62	RE	0.142	-	-	-	± 0.020	25.0	Fc⁺ / Fc	MeCN	-	Pt	Fc⁺ / Fc	2FB	Pt	Fcpf , Fc	Fcpf , Fc	OCV; ILSB	Tanja MA	3

Fc⁺ / Fc

MeCN

Pt

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
42	RE	-	-1.352	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	Pt	Cc⁺ / Cc	MeCN	Pt	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4
43	RE	-	-2.297	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	Pt	Cc / Cc^-	MeCN	Pt	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Fc⁺ / Fc

MeCN

Pt

LiClO₄

0.200

-

5

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
29	WE	0.310	-	-	-	-	25.0	Fc⁺ / Fc	MeCN	LiClO₄	Pt	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	Fc	SCE	Chronopotentiometry	T. Kuwana, D.E. Bublitz, G. Hoh, J. Am. Chem. Soc. 1960, 82, 5811-5817. DOI: 10.1021/ja01507a011	6

Fc⁺ / Fc

MeCN

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
9	RE	-	0.870	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][pf]	Pt	NO⁺ / NO	MeCN	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
18	WE	-	-0.020	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	MeCN	Ag	Fcpf	Agpf	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4
67	RE	-	-	1.000	-	± 0.100	300.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	MeCN (1.0)	Ag	Agpf	Fcpf , Fc	trst	test	4

Fc⁺ / Fc

MeCN

Pt

[N₂₂₂₂][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
50	RE	-	0.322	-	-	± 0.003	25.0	Fc⁺ / Fc	MeCN	[N₂₂₂₂][PF₆]	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁴⁺	MeCN	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	-	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	4
51	RE	-	0.610	-	-	± 0.003	25.0	Fc⁺ / Fc	MeCN	[N₂₂₂₂][PF₆]	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁶⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺	MeCN	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	-	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	4

Fc⁺ / Fc

MeCN

Pt

1-Ethyl-3-methylimidazolium chloride

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
72	RE	-	1.000	-	-	-	-	Fc⁺ / Fc	MeCN	1-Ethyl-3-methylimidazolium chloride	Pt	Ag⁺ / Ag	MeCN (1.0)	Ag	Agpf	Fcpf , Fc	CV	test	4

Fc⁺ / Fc

MeCN

glassy carbon

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
38	RE	-	-1.348	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	glassy carbon	Cc⁺ / Cc	MeCN	glassy carbon	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4
39	RE	-	-2.297	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][BF₄]	glassy carbon	Cc / Cc^-	MeCN	glassy carbon	CcPF₆	AgNO₃	CV	R.S. Stojanovic, A.M. Bond, Anal. Chem. 1993, 65, 56-64. DOI: 10.1021/ac00049a012	4

Fc⁺ / Fc

MeCN

n.a.

[N₄₄₄₄][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
28	WE	-	0.400	-	-	-	25.0	Fc⁺ / Fc	MeCN	[N₄₄₄₄][PF₆]	n.a.	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	-	SCE	CV	N.G. Connelly, W.E. Geiger, Chem. Rev. 1996, 96, 877-910. DOI: 10.1021/cr940053x	6

🔗

Fc⁺ / Fc

PC

-

0.478

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Fc⁺ / Fc

PC

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
25	WE	-	-0.491	-	-	-	25.0	Fc⁺ / Fc	PC	[N₄₄₄₄][pf]	Pt	Ag⁺ / Ag	PC	Ag	Fcpf	Agpf	CV	gemessen Timo	4

Fc⁺ / Fc

PC

Pt

[N₂₂₂₂][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
27	WE	-	0.359	-	-	-	25.0	Fc⁺ / Fc	PC	[N₂₂₂₂][PF₆]	Pt	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	-	SCE	DPV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	6

Fc⁺ / Fc

PC

n.a.

[N₄₄₄₄][PF₆]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
26	WE	-	0.380	-	-	-	25.0	Fc⁺ / Fc	PC	[N₄₄₄₄][PF₆]	n.a.	Hg₂Cl₂ / Cl^- , Hg	H₂O	Hg	-	SCE	CV	N.G. Connelly, W.E. Geiger, Chem. Rev. 1996, 96, 877-910. DOI: 10.1021/cr940053x	6

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

H⁺ / H₂

H₂O

0.000

-

± 0.000

1

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

H⁺ / H₂

H₂O

Pt

-

1

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
24	RE	0.799	-	-	-	-	25.0	H⁺ / H₂	H₂O	-	Pt	Ag⁺ / Ag	H₂O	Ag	-	-	OCV	CRC	1

H⁺ / H₂

H₂O

Pt

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
56	RE	0.504	-	-	-	± 0.010	25.0	H⁺ / H₂	H₂O	-	Pt	H⁺ / H₂	MeCN	Pt	H₂ , HNTf₂	H₂ , HCl	OCV; ILSB	Niklas	2
117	RE	0.503	-	-	-	± 0.002	25.0	H⁺ / H₂	H₂O	-	Pt	H⁺ / H₂	MeCN	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
118	RE	0.345	-	-	-	± 0.002	25.0	H⁺ / H₂	H₂O	-	Pt	H⁺ / H₂	MeFo	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
119	RE	0.070	-	-	-	± 0.002	25.0	H⁺ / H₂	H₂O	-	Pt	H⁺ / H₂	EtOH	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
120	RE	0.080	-	-	-	± 0.002	25.0	H⁺ / H₂	H₂O	-	Pt	H⁺ / H₂	MeOH	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2

🔗

H⁺ / H₂

MeCN

0.504

-

± 0.010

2

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

H⁺ / H₂

MeCN

Pt

-

[N₂₂₂₅][NTf₂]

2

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
56	WE	0.504	-	-	-	± 0.010	25.0	H⁺ / H₂	MeCN	-	Pt	H⁺ / H₂	H₂O	Pt	H₂ , HNTf₂	H₂ , HCl	OCV; ILSB	Niklas	2
57	WE	-0.031	-	-	-	± 0.010	25.0	H⁺ / H₂	MeCN	-	Pt	Ag⁺ / Ag	MeCN	Ag	H₂ , HNTf₂	Agpf	OCV; ILSB	Razan	2
117	WE	0.503	-	-	-	± 0.002	25.0	H⁺ / H₂	MeCN	-	Pt	H⁺ / H₂	H₂O	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
121	RE	-0.158	-	-	-	± 0.002	25.0	H⁺ / H₂	MeCN	-	Pt	H⁺ / H₂	MeFo	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
122	RE	-0.433	-	-	-	± 0.002	25.0	H⁺ / H₂	MeCN	-	Pt	H⁺ / H₂	EtOH	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
123	RE	-0.423	-	-	-	± 0.002	25.0	H⁺ / H₂	MeCN	-	Pt	H⁺ / H₂	MeOH	Pt	-	-	OCV; ILSB	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2
127	RE	0.034	-	-	-	± 0.010	25.0	H⁺ / H₂	MeCN	-	Pt	Ag⁺ / Ag	MeCN	Ag	Agpf	HNTf₂ , H₂	OCV	R. Stroh, N. Gebel, T. Kienzle, V. Radtke, I. Krossing, ChemPhysChem 2026, 27. DOI: 10.1002/cphc.202500349	2

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

Hg₂Cl₂ / Cl^- , Hg

H₂O | MeCN

0.299

-

± 0.014

6

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Hg₂Cl₂ / Cl^- , Hg

H₂O | MeCN

Hg

[N₄₄₄₄][BF₄]

0.100

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
45	RE	-	-0.980	-	-	± 0.001	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][BF₄]	Hg	Cc⁺ / Cc	MeCN	DME	CcBr₃	SCE	CV	S. Gubin, S. Smirnova, L. Denisovich, Journal of Organometallic Chemistry 1971, 30, 257-265. DOI: 10.1016/S0022-328X(00)90205-5	6
46	RE	-	-1.920	-	-	± 0.001	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][BF₄]	Hg	Cc / Cc^-	MeCN	DME	CcBr₃	SCE	CV	S. Gubin, S. Smirnova, L. Denisovich, Journal of Organometallic Chemistry 1971, 30, 257-265. DOI: 10.1016/S0022-328X(00)90205-5	6

Hg₂Cl₂ / Cl^- , Hg

H₂O | MeCN

Hg

LiClO₄

0.200

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
29	RE	0.310	-	-	-	-	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	LiClO₄	Hg	Fc⁺ / Fc	MeCN	Pt	Fc	SCE	Chronopotentiometry	T. Kuwana, D.E. Bublitz, G. Hoh, J. Am. Chem. Soc. 1960, 82, 5811-5817. DOI: 10.1021/ja01507a011	6

Hg₂Cl₂ / Cl^- , Hg

H₂O | MeCN

Hg

[N₂₂₂₂][PF₆]

0.100

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
48	RE	-	0.722	-	-	± 0.003	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₂₂₂₂][PF₆]	Hg	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁴⁺	MeCN	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	SCE	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	6
49	RE	-	1.005	-	-	± 0.003	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₂₂₂₂][PF₆]	Hg	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁶⁺ / (bpy)₂RuCl(pyz)Ru(NH₃)₄(py) ⁵⁺	MeCN	Pt	(bpy)₂RuCl(pyz)Ru(NH₃)₄(py)(PF₆)₃ , Fe(bpy)₃(PF₆)₃	SCE	CV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	6

Hg₂Cl₂ / Cl^- , Hg

H₂O | MeCN

Hg

[N₄₄₄₄][PF₆]

0.100

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
28	RE	-	0.400	-	-	-	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Fc⁺ / Fc	MeCN	n.a.	-	SCE	CV	N.G. Connelly, W.E. Geiger, Chem. Rev. 1996, 96, 877-910. DOI: 10.1021/cr940053x	6
30	RE	0.128	-	-	-	± 0.002	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Ag⁺ / Ag	MeCN	Ag	AgClO₄	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
31	RE	0.237	-	-	-	± 0.002	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Ag⁺ / Ag	MeCN	Ag	AgNO₃	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
32	RE	0.225	-	-	-	± 0.002	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Ag⁺ / Ag	MeCN	Ag	AgNO₃	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
33	RE	0.121	-	-	-	± 0.002	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Ag⁺ / Ag	MeCN	Ag	AgNO₃	SCE	OCV	V.V. Pavlishchuk, A.W. Addison, Inorg. Chim. Acta 2000, 298, 97-102. DOI: 10.1016/S0020-1693(99)00407-7	6
44	RE	-	-0.905	-	-	-	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Cc⁺ / Cc	MeCN	dme?	CcPF₆	SCE	CV	T. Gennett, D.F. Milner, M.J. Weaver, J. Phys. Chem. 1985, 89, 2787-2794. DOI: 10.1021/j100259a018	6
47	RE	-	-0.945	-	-	± 0.001	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Cc⁺ / Cc	MeCN	Pt	-	SCE	CV	U. Koelle, Journal of Organometallic Chemistry 1978, 152, 225-228. DOI: 10.1016/S0022-328X(00)91926-0	6
52	RE	-	-0.770	-	-	-	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| MeCN	[N₄₄₄₄][PF₆]	Hg	Cr(C₆H₆)⁺ / Cr(C₆H₆)	MeCN	dme?	Cr(C₆H₆)	SCE	CV	T. Gennett, D.F. Milner, M.J. Weaver, J. Phys. Chem. 1985, 89, 2787-2794. DOI: 10.1021/j100259a018	6

🔗

Hg₂Cl₂ / Cl^- , Hg

H₂O | PC

-

0.098

-

6

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

Hg₂Cl₂ / Cl^- , Hg

H₂O | PC

Hg

[N₂₂₂₂][PF₆]

0.100

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
27	RE	-	0.359	-	-	-	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| PC	[N₂₂₂₂][PF₆]	Hg	Fc⁺ / Fc	PC	Pt	-	SCE	DPV	J.P. Chang, E.Y. Fung, J.C. Curtis, Inorg. Chem. 1986, 25, 4233-4241. DOI: 10.1021/ic00243a034	6

Hg₂Cl₂ / Cl^- , Hg

H₂O | PC

Hg

[N₄₄₄₄][PF₆]

0.100

-

6

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
26	RE	-	0.380	-	-	-	25.0	Hg₂Cl₂ / Cl^- , Hg	H₂O \| PC	[N₄₄₄₄][PF₆]	Hg	Fc⁺ / Fc	PC	n.a.	-	SCE	CV	N.G. Connelly, W.E. Geiger, Chem. Rev. 1996, 96, 877-910. DOI: 10.1021/cr940053x	6

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

MB⋅⁺ / MB

1FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

MB⋅⁺ / MB

1FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
19	WE	-	0.690	-	-	-	25.0	MB⋅⁺ / MB	1FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	1FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

MB⋅⁺ / MB

2FB

-

1.347

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

MB⋅⁺ / MB

2FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
20	WE	-	0.690	-	-	-	25.0	MB⋅⁺ / MB	2FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	2FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

MB⋅⁺ / MB

3FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

MB⋅⁺ / MB

3FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
21	WE	-	0.690	-	-	-	25.0	MB⋅⁺ / MB	3FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	3FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

MB⋅⁺ / MB

4FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

MB⋅⁺ / MB

4FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
22	WE	-	0.690	-	-	-	25.0	MB⋅⁺ / MB	4FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	4FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

MB⋅⁺ / MB

5FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

MB⋅⁺ / MB

5FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
23	WE	-	0.690	-	-	-	25.0	MB⋅⁺ / MB	5FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	5FB	Pt	MB	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

NO⁺ / NO

1FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

1FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
1	WE	-	1.110	-	-	-	25.0	NO⁺ / NO	1FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	1FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

2FB

-

1.887

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

2FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
2	WE	-	1.230	-	-	-	25.0	NO⁺ / NO	2FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	2FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

3FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

3FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
3	WE	-	1.420	-	-	-	25.0	NO⁺ / NO	3FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	3FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

4FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

4FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
4	WE	-	1.520	-	-	-	25.0	NO⁺ / NO	4FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	4FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

5FB

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

5FB

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
5	WE	-	1.470	-	-	-	25.0	NO⁺ / NO	5FB	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	5FB	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

DCE

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

DCE

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
7	WE	-	1.230	-	-	-	25.0	NO⁺ / NO	DCE	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	DCE	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

DCM

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

DCM

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
6	WE	-	1.400	-	-	-	25.0	NO⁺ / NO	DCM	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	DCM	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

DMF

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

DMF

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
8	WE	-	0.540	-	-	-	25.0	NO⁺ / NO	DMF	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	DMF	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

🔗

NO⁺ / NO

MeCN

-

1.386

-

4

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

NO⁺ / NO

MeCN

Pt

[N₄₄₄₄][pf]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
9	WE	-	0.870	-	-	-	25.0	NO⁺ / NO	MeCN	[N₄₄₄₄][pf]	Pt	Fc⁺ / Fc	MeCN	Pt	NOpf	Fcpf , Fc	CV	C. Armbruster, M. Sellin, M. Seiler, T. Würz, F. Oesten, M. Schmucker, T. Sterbak, J. Fischer, V. Radtke, J. Hunger, I. Krossing, Nat Commun 2024, 15. DOI: 10.1038/s41467-024-50669-3	4

Ideal Half Cells

▶

Select

Redoxsystem

Solvent

E^°_abs / V

E_{1/2, abs} / V

E_{pa, abs} / V

E_{pc, abs} / V

Uncertainty / V

Quality

🔗

[Ru(bpy)₃]³⁺ / [Ru(bpy)₃]²⁺

MeCN

-

None

Real Half Cells

▶

Redoxsystem

Solvent

electrode material

conducting electrolyte

c(conducting electrolyte) / M

c(RE) / M

IL

Quality

[Ru(bpy)₃]³⁺ / [Ru(bpy)₃]²⁺

MeCN

Pt

[N₄₄₄₄][BF₄]

0.100

-

4

Measurements

ID	Role	E^° / V	E_1/2 / V	E_pa / V	E_pc / V	Uncertainty / V	T / °C	Redoxsystem	Solvent	conducting electrolyte	electrode material	Redoxsystem OE	Solvent OE	electrode material OE	Used Substances (AE)	Used Substances (RE)	Method	Source	Quality
55	WE	-	1.290	-	-	-	25.0	[Ru(bpy)₃]³⁺ / [Ru(bpy)₃]²⁺	MeCN	[N₄₄₄₄][BF₄]	Pt	AgCl / Cl^- , Ag	H₂O	Ag	-	SSCE	CV	J. G. Gaudiello, P. R. Sharp, A. J. Bard, J. Am. Chem. Soc. 1982, 104, 6373.	6

Ideal Half Cells

▶	Select	Redoxsystem	Solvent	E^°_abs / V	E_{1/2, abs} / V	E_{pa, abs} / V	E_{pc, abs} / V	Uncertainty / V	Quality

Redoxsystems on the absolute Scale

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