This page allows you to browse all measurements in the database. Please note that these are the experimental values provided, not the values from the Solvent-Independent Unified Aqueous Redox Scale.
| Redox System Working Electrode (WE) | Solvent WE | Redox System Reference Electrode (RE) | Solvent RE | E° or E°' / V | E1/2 / V | Epa / V | Epc / V | Conducting Electrolyte | Ionic Liquid | Reference | Method | WE Material | RE Material | c(RE) / M | T / °C | Quality | Comment | Used Substances WE | Used Substances RE |
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| ( η5-C9H7)Ir(CO)(η2-C8H14)+ / ( η5-C9H7)Ir(CO)(η2-C8H14) | DCM | Fc+ / Fc | DCM | 0.38 | - | - | - | [N4444][PF6] (0.1 M) | - |
R.S. Koefod, C. Xu, W. Lu, J.R. Shapley, M.G. Hill, K.R. Mann, <i>J. Phys. Chem.</i> <b>1992</b>, <i>96</i>, 2928-2930.
https://doi.org/10.1021/j100186a029 |
CV | Pt | - | - | 25.0 | 4 | irreversible; Ep given | - | - |
| ((p-Cl)TPPP)Ni / ((p-Cl)TPPP)Ni- | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | -1.18 | - | - | - | [N4444][ClO4] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | - | - | - |
| ((p-Cl)TPPP)Ni / ((p-Cl)TPPP)Ni- | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | -1.26 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Cl)TPPP)Ni+ / ((p-Cl)TPPP)Ni | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 1.10 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Cl)TPPP)Ni- / (TEtP)Ni | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 0.85 | - | - | - | [N4444][ClO4] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Cl)TPPP)Ni- / (TEtP)Ni | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 0.81 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Cl)TPPP)Ni2+ / ((p-Cl)TPPP)Ni | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 1.13 | - | - | - | [N4444][ClO4] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | 2 e- Prozess; keine Korrektur für LJP enthalten | - | - |
| ((p-Cl)TPPP)Ni2+ / ((p-Cl)TPPP)Ni+ | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 1.34 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni / ((p-Et2N)TPP)Ni- | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | -1.36 | - | - | - | [N4444][ClO4] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni / ((p-Et2N)TPP)Ni- | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | -1.43 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni+ / ((p-Et2N)TPP)Ni | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 0.63 | - | - | - | [N4444][ClO4] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni+ / ((p-Et2N)TPP)Ni | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 0.56 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni2+ / ((p-Et2N)TPP)Ni+ | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 1.11 | - | - | - | [N4444][ClO4] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni2+ / ((p-Et2N)TPP)Ni+ | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 1.07 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| ((p-Et2N)TPP)Ni3+ / ((p-Et2N)TPP)Ni2+ | DCM | Hg2Cl2 / Cl- , Hg | H2O | DCM | 1.33 | - | - | - | [N4444][PF6] (0.1 M) | - |
D. Chang, T. Malinski, A. Ulman, K.M. Kadish, <i>Inorg. Chem.</i> <b>1984</b>, <i>23</i>, 817-824.
https://doi.org/10.1021/ic00175a006 |
CV | Pt | - | - | 25.0 | 6 | Keine Korrektur für LJP enthalten | - | - |
| (3,5-difluorophenyl)((trimethylsilyl)ethynyl)iodonium / (3,5-difluorophenyl)((trimethylsilyl)ethynyl)iodonium | THF | Fc+ / Fc | THF | -0.97 | - | - | - | [N4444][PF6] (0.1 M) | - |
F. Debbeler, D. Jenisch, C. Souilah, P. Moths, S. Ivlev, A. Casitas, <i>Synthesis</i> <b>2025</b>, <i>57</i>, 2946-2962.
https://doi.org/10.1055/a-2650-7789 |
CV | glassy carbon | - | - | 25.0 | 4 | Ep_c/2 angegeben, irreversiebel im Paper außerdem Ep_c angegeben | - | - |
| (3,5-difluorophenyl)((trimethylsilyl)ethynyl)iodonium / (3,5-difluorophenyl)((trimethylsilyl)ethynyl)iodonium | MeCN | Fc+ / Fc | MeCN | -0.71 | - | - | - | [N4444][PF6] (0.1 M) | - |
F. Debbeler, D. Jenisch, C. Souilah, P. Moths, S. Ivlev, A. Casitas, <i>Synthesis</i> <b>2025</b>, <i>57</i>, 2946-2962.
https://doi.org/10.1055/a-2650-7789 |
CV | glassy carbon | - | - | 25.0 | 4 | Ep_c/2 angegeben, irreversiebel im Paper außerdem Ep_c angegeben | - | - |
| (3-fluorophenyl)((trimethylsilyl)ethynyl)iodonium+ / (3-fluorophenyl)((trimethylsilyl)ethynyl)iodonium | THF | Fc+ / Fc | THF | -0.91 | - | - | - | [N4444][PF6] (0.1 M) | - |
F. Debbeler, D. Jenisch, C. Souilah, P. Moths, S. Ivlev, A. Casitas, <i>Synthesis</i> <b>2025</b>, <i>57</i>, 2946-2962.
https://doi.org/10.1055/a-2650-7789 |
CV | glassy carbon | - | - | 25.0 | 4 | Ep_c/2 angegeben, irreversiebel im Paper außerdem Ep_c angegeben | - | - |
| (3-fluorophenyl)((trimethylsilyl)ethynyl)iodonium+ / (3-fluorophenyl)((trimethylsilyl)ethynyl)iodonium | MeCN | Fc+ / Fc | MeCN | -0.66 | - | - | - | [N4444][PF6] (0.1 M) | - |
F. Debbeler, D. Jenisch, C. Souilah, P. Moths, S. Ivlev, A. Casitas, <i>Synthesis</i> <b>2025</b>, <i>57</i>, 2946-2962.
https://doi.org/10.1055/a-2650-7789 |
CV | glassy carbon | - | - | 25.0 | 4 | Ep_c/2 angegeben, irreversiebel im Paper außerdem Ep_c angegeben | - | - |
| (3-nitrophenyl)((trimethylsilyl)ethynyl)iodonium+ / (3-nitrophenyl)((trimethylsilyl)ethynyl)iodonium | THF | Fc+ / Fc | THF | -0.90 | - | - | - | [N4444][PF6] (0.1 M) | - |
F. Debbeler, D. Jenisch, C. Souilah, P. Moths, S. Ivlev, A. Casitas, <i>Synthesis</i> <b>2025</b>, <i>57</i>, 2946-2962.
https://doi.org/10.1055/a-2650-7789 |
CV | glassy carbon | - | - | 25.0 | 4 | Ep_c/2 angegeben, irreversiebel im Paper außerdem Ep_c angegeben | - | - |